Analysis of photovoltage decay transients in dye-sensitized solar cells
Article Abstract:
The quasi-static approximation can be used to simplify the theoretical treatment of the open circuit photovoltage decay of dye-sensitized nanostructured solar cells (DSCs), as it removes the need to treat the kinetics of trapping and detrapping explicitly and leads to a straightforward analytical solution in the case of an exponential trap distribution. The numerical calculations have shown that the quasi-static approximation is a useful and simple approach to data analysis, but deviations at short times are important, particularly if the density of trapping states is small.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Grain morphology and trapping effects on electron transport in dye-sensitized nanocrystalline solar cells
Article Abstract:
The combined effects of grain morphology and electron trapping on the transient response of photoelectrons moving through the TiO(sub 2) grains in a dye-sensitized nanocrystalline solar cell are presented using a multitime-scale random walk Monte Carlo model. It is shown that the constrictions at the grain necks slow the electrons, making trapping more likely and hence further delaying their passage to the extracting electrode.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
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Influence of grain morphology on electron transport in dye sensitized nanocrystalline solar cells
Article Abstract:
A Monte Carlo model of electron transport in mesoporous films of TiO2 particles is presented in which electrons execute a random walk through a chain of spherical grains with traps at the surface of the grains. It is used to simulate transient photocurrents in dye sensitized nanocrystalline solar cells.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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