Catalytic influence of Pt monolayer islands on the hydrogen electrochemistry of Ru(0001) studied by ultrahigh vacuum scanning tunneling microscopy and cyclic voltammetry
Article Abstract:
An investigation on the electrochemical behavior of well-defined Pt-modified Ru(0001) electrodes in perchloric acid solution is presented by cyclic voltammetry. The study concluded that hydrogen adsorption on the strained Pt monolayer is very weak, much weaker than on bulk Pt, which agrees well with theoretical predictions.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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High-temperature sorbents for CO2 made of alkali metals doped on CaO supports
Article Abstract:
The basic sorbents based on CaO are synthesized, characterized, and tested for the high capacity and selectivity for CO2 and selected gas mixtures simulating flue gas. The highly promising sorbents based on Cs/CaO, that demonstrated zero affinity for N2 and O2 and very low affinity for water, are obtained from the results.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Simulated 'air bleed' oxidation of absorbed CO on carbon supported pt. part 2. Electrochemical measurements of hydrogen peroxide formation during O2 reduction in a double-disk electrode dual thin-layer flow cell
Article Abstract:
The results of potentiodynamic and transient potentiostatic measurements on the O2 reduction reaction (ORR) kinetics and on the CO adlayer oxidation in O2-saturated solution CO(sub ad)-covered Pt/Vulcan electrodes are described. The resulting data under fuel cell relevant conditions are presented.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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- Abstracts: Ultrathin wagon-wheel-like [TiO.sub.x] phases on Pt(111): A combined low-energy electron diffraction and scanning tunneling microscopy investigation
- Abstracts: Influence of oxygen on the UV-photocatalyzed generation of pyrene cation radicals in the zeolites X and Y. Theoretical investigation of the dimerization of linear alkenes catalyzed by acidic zeolites
- Abstracts: Influence of polymer molecular weight on the chemical modifications induced by UV laser ablation. Product formation in laser irradiation of doped poly(methyl methacrylate) at 248 nm: implications for chemical effect in UV ablation
- Abstracts: Measurement of lateral charge propagation in [Os(bpy)2(PVP)nCl]Cl thin films: a scanning electromechanical microscopy approach
- Abstracts: Measurement of lateral charge propagation in [Os(bpy)2(PVP)nCl]Cl thin films: a scanning electromechanical microscopy approach. part 2