Effect of HNO3 and HCl on HDO diffusion on crystalline D2O ice multilayers
Article Abstract:
HDO diffusion kinetics on ultrathin and HCl-dosed crystalline D2O ice multilayers were studied through a combination of laser-induced thermal desorption probing and isothermal desorption depth profiling. The HDO diffusion rates were radically modified by the presence of HNO3 and HCl. The effects of HNO3 on the HDO diffusion rates may be ascribed to the production of stable HNO3-hydrate cages that restrict HDO migration.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
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Dynamical behavior of anion-water and water-water hydrogen bonds in aqueous electrolyte solutions: a molecular dynamics study
Article Abstract:
The dynamics of anion-water and water-water hydrogen bonds in aqueous alkali halide solutions by means of molecular dynamics simulations is investigated. The results are obtained for solutions containing a single chloride or a single bromide ion and also for a concentrated solution of 3.35 M NaCl in water.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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