Effect of humidity on the supramolecular structure of cotton, studied by quantitative spin probing
Article Abstract:
The effects of water content on the physicochemical properties of the amorphous regions in cotton are investigated by measuring the electron paramagnetic resonance (EPR) of TEMPOL nitroxide radicals, deposited in cotton at different loadings as a function of the relative humidity (RH) temperature. The effects are rationalized on the basis of microdomains of different character within cotton, reflecting the variation in pore sizes (0.5-8 nm) and the relaxation behavior of the cellulose chains.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
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Pulsed field gradient NMR study of the diffusion of H2O and polyethylene glycol polymers in the supramolecular structure of wet cotton
Article Abstract:
Pulsed Field Gradient (PFG) NMR study of the diffusion of H2O, PEG200, PEG1500, PEG8000, and PEG20000 in wet cotton fibers and H2O in wet cotton linters are presented. PFG NMR study has shown new insights and has highlighted some of the strengths and weakness of PFG NMR when applied to relatively complicated systems such as cotton.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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