Electrochemistry of nickel and copper beta-octahalogeno-meso-tetraarylporphyrins. Evidence for important role played by saddling-induced metal[d(sub x(super 2)-y(super 2)]-porphyrin ("a(sub 2u)") orbital interactions
Article Abstract:
An electrochemical study of substituent effects in Ni(II) and Cu(II) complexes of a series of beta-octahalogeno-meso-tetrakis is presented. The study of substituent effects in saddled Ni and Cu porphyrins has revealed a variety of interesting differences between the two families of compounds.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
Industrial Organic Chemicals, Cyclic Crude and Intermediate Manufacturing, Porphyrins, Copper
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
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Experimental and theoretical studies of the multistability in the electroreduction of the nickel(II)-N(sub 3)(super -) complexes at a streaming mercury electrode
Article Abstract:
An analogous phenomenon for the azide complexes for nickel (II) is described. The thermodynamic and kinetic parameters of the studied redox system are determined by a comparison of the experimental and theoretical dependencies.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Analysis, Thermodynamics, Structure
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
User Contributions:
Comment about this article or add new information about this topic:
Subjects list: Research, Nickel, Chemistry, Physical and theoretical, Physical chemistry, Chemical properties
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