Infrared study of ZrO(sub 2) surface sites using adsorbed probe molecules. 2. Dimethyl ether adsorption

Article Abstract:

The properties of two types of surface of OH species, terminal and bridged, as well as corresponding vacant sites on zirconium hydroxide at 573 K are studied using dimetyl ether adsoprtion as an IR molecular probe. The preferential reaction of acidic carbon dioxide with the t-OH group demonstrated that the t-OH group acts as a base, in which t-OH oxygen lone pairs are favorable in the electrophilic reaction.

All Other Basic Inorganic Chemical Manufacturing, Industrial organic chemicals, not elsewhere classified, Industrial inorganic chemicals, not elsewhere classified, Zirconium Compounds, Methyl Ether, Hydroxides, Atomic properties

---

Collisions of silylium cations with hydroxyl-terminated and other self-assembled monolayer surfaces: reactions, dissociation, and surface characterization

Article Abstract:

Silylium cations undergo dissociative ion/surface reactions in the course of low-energy collisions with hydroxyl-terminated, hydrocarbon and fluorocarbon elf-assembled monolayer surfaces. Thermodynamic estimates regarding charge exchange between the surface and the projectile ion are consistent with the relative amounts of chemically sputtered products observed for each of the surfaces.

Industrial Organic Chemicals, Fluorocarbons, Hydrocarbons, Dissociation, Dissociation reactions

---

Microdisk electrode voltammetry: theoretical characterization and experimental verification of a novel electrocataltic mechanism

Article Abstract:

A numerical method is used to characterize the steady-state voltammetry at microdisk electrodes of a new electrocatalytic reaction. The numerical method for simulating this reaction scheme is based on the finite-difference formulation of coupled mass transport and kinetic equations in oblate spherical coordinates.

Electrodes, Voltammetry

Similar abstracts:

• Abstracts: Dynamic and equilibrium surface pressure of adsorbed dodecanol monolayers at the air/water interface. Thermodynamic and textural characterization of DPPG phospholipid monolayers
• Abstracts: Characterization of acid sites in zeolitic and other inorganic systems using solid-state 31P NMR of the probe molecule trimethylphosphine oxide
• Abstracts: Single-crystal synchrotron radiation x-ray diffraction study of B and Ga silicates compared to a purely siliceous MFI: a discussion of the heteroatom distribution
• Abstracts: Dynamic determination of vapor/water interface adsorption for volatile hydrophobic organic compounds (VHOs) using axisymmetric drop shape analysis: Procedure and analysis of benzene adsorption
• Abstracts: Sticking probabilities in adsorption of alkanethiols from liquid ethanol solution onto goldR. part 2

This website is not affiliated with document authors or copyright owners. This page is provided for informational purposes only. Unintentional errors are possible.