Probing solute clustering in supercritical solutions using solvatochromic parameters
Article Abstract:
The study results for three supercritical solutions containing solutes at different polarities reveal that there is a direct correlation between the change in the hydrogen-bond-donating ability and polarizability for all solutes and all pressures and concentrations which changes with the amount of solvent required to solvate the solute.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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Equilibrium reactions in supercritical difluoromethane
Article Abstract:
The application of the in situ dielectometry technique to follow the extent of two equilibrium reactions in supercritical difluoromethane is demonstrated. The advantages and disadvantages of applying this technique to follow the reactions are discussed.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Effect of solutes on the viscosity of supercritical solutions
Article Abstract:
A study results show that solutes could impart significant structure to supercritical solutions which results in unexpectedly high solution viscosity at pressures close to critical value.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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