Raman micro spectrometry as a new approach to the investigation of molecular recognition in solids: chlorofornm-cryptophane complexes
Article Abstract:
A polarized Raman micro spectrometry study of micro crystals of cryptophane-A, selectively deuterated cryptophane-A, bis-cryptophane, and cryptophane-E encapsulating chloroform molecules is presented. By x-ray diffraction analysis, the crystallographic structures of these different molecular entities are isolated.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Kinetics of molecular transport in a nanoporous crystal studied by confocal Raman microspectrometry: single-file diffusion in a densely filled tunnel
Article Abstract:
Confocal Raman microspectrometry is used for probing the kinetic aspects of the guest exchange process in a urea inclusion compound. The transport of the new pentadecane guest molecules along the tunnel has displayed a linear dependence on time, with the rate of the process in the region of 70-100 nm [s.sup.-1].
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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Distribution of hydrophobic ions and their counterions at an aqueous-liquid-liquid interface. A molecular dynamics investigation
Article Abstract:
The molecular dynamics study on the distribution of spherical hydrophobic ions and hydrophilic counterions at a water-'oil' surface, where 'oil' is modeled by chloroform is discussed. Also discussed are the implications of the results of the mechanism of assisted ion transfer.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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