Reactivity of organic compounds inside micelles embedded in sol-gel glass. Kinetics of summarization of azobenzene inside C/TAB and SDS micelles

Article Abstract:

The interplay of differently charged micelles and surrounding silica matrix and their joint effects on the reactivity of compounds entrapped in the micelles are studied. The result reveals that partioning of the dopant between the micelle/silica glass and the external liquid influences the reactivity of dopant molecules.

Basic Chemical Manufacturing, Organic Chemicals, Industrial sand, Silica & Silica Sand, Industrial Sand Mining, Silica, Organic compounds, Chemistry, Physical and theoretical, Physical chemistry, Micelles

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Stable charge-transfer complexes versus contact complexes. Application to the interaction of fullerenes with aromatic hydrocarbons

Article Abstract:

The methods of calculation of the equilibrium constants and electronic absorption spectra of charge-transfer complexes are discussed. The simple contact complexes have been formed, for which several spectroscopic parameters is obtained.

Cyclic Crude and Intermediate Manufacturing, Aromatic Hydrocarbons, Charge transfer, Fullerenes

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