Relationships between nonadiabatic bridged intramolecular, electrochemical, and electrical electron-transfer processes
Article Abstract:
The method to determine the correlation between the rate constants for electron transfer in donor-bridge-acceptor and electrode-bridge-acceptor systems and resistances across metal-bridge-electrode and metal-bridge-tip junctions is described. A simple approach to evaluate consistency between the different rate constant and resistance measurements through molecular bridges in various electron-transfer situations is presented.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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A comparison between interfacial electron-transfer rate constants at metallic and graphite electrodes
Article Abstract:
The Fermi's golden rule formalism was used to derive the rate constant for interfacial electron transfer from a semimetallic electrode, such as highly ordered pyrolytic graphite (HOPG), to a redox couple in solution. The approach could also be used to provide a framework for understanding electrochemical kinetics measurements for a series of outer-sphere redox systems at highly ordered graphite electrode surfaces.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Reactions of etched, single crystal (111)B-oriented InP to produce functionalized surfaces with low electrical defect densities
Article Abstract:
It has been possible to identify an apparently general synthetic strategy for the functionalization of InP surfaces. The etched InP surfaces produced survey scan XP spectra that were very close to those expected for a 1:1 In/P stoichiometry.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
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- Abstracts: X-ray absorption spectroscopy of Mn/Co/TiO2 Fischer-Tropsch catalysts: Relationships between preparation method, molecular structure, and catalyst performance
- Abstracts: Graphical analysis of electrochemical impedance spectroscopy of two consecutive irreversible electron transfers. 1. Theoretical study of the anodic dissolution of metals