Structural characteristics of a 0.23 mole fraction aqueous solution of tetrahydrofuran at 20 degree Celsius
Article Abstract:
Hydrogen/deuterium isotopic substitution neutron diffraction techniques are used to measure the structural correlation functions in a 0.23 mole fraction solution of tetrahydrofuran in water at room temperature. Despite the small size of the solvent water molecules, the 0.23 mole fraction aqueous solution is still found to contain small voids akin to those in pure liquid tetrahydrofuran.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
User Contributions:
Comment about this article or add new information about this topic:
Structure and thermal expansivity of tetrahydrofuran deuterate determined by neutron powder diffraction
Article Abstract:
The crystal structure of tetrahydrofuran deuterate, a clathrate hydrate, is refined from neutron powder diffraction data at five temperatures in the range 7-265K. The most pronounced structural changes occur in a similar regime of T as changes in guest dynamics observed in spectroscopic and thermodynamic studies.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
User Contributions:
Comment about this article or add new information about this topic:
Electrochemical behavior of sodium anions
Article Abstract:
The electrochemical behavior of sodium analyte species is experimented in 0.1 M TBAP and in electrolyte-free tetrahydrofuran solutions at room temperature. The results obtained from electrochemical studies of sodium electrodes and of sodium salts at a mercury film electrode are also presented.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Clustering structure of aqueous solution of kinetic inhibitor of gas hydrates. Effect of shrinking microbubble on gas hydrate formation
- Abstracts: Structural relation properties of hydrothermally stable functionalized mesoporous organosilicas and catalysis
- Abstracts: Structural anomalies of Rb and Br ionic nanosolutions in hydrophobic slit-shaped solid space as revealed by the EXAFS technique
- Abstracts: Polyelectrolyte behavior of an interpolyelectrolyte complex formed in aqueous solution of a charged dendrimer and sodium poly(L-glutamate)
- Abstracts: Structural characterization of CeO2-TiO2 and V2O5/CeO2-TiO2 catalysts by Raman and XPS techniques