Temperature dependence of rate constants for Tb (super 3plus) (super 5) D (sub 3) cross relaxation in symmetric Tb (super 3plus) pairs in Tb-doped CsCdBr (sub 3), CsMgBr (sub 3), CsMgCl (sub 3)

Article Abstract:

A study was conducted which strongly indicated that Tb (super 5) D (sub 3) cross relaxation in symmetrical Tb (super 3plus)-Tb (super 3plus) pairs in CsCdBr (sub 3), CsCdBr (sub 3), and CsMgCl (sub 3) id sue to resonance between zero-phonon crystal-field transitions on the donor and acceptor. Cross relaxation in these systems is therefore, "resonant"' in the sense that only donor and acceptor transition with significant direct overlap of the zero-phonon spectral lines participate in active transfer mechanisms,

Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Alkalies and chlorine, Alkalies and Chlorine Manufacturing, Cadmium, Cesium, Chlorine, Magnesium, Magnesium (Metal), Terbium

---

Hydrogen elimination and solid-state reaction in hydrogen-bonded systems under pressure: the case of HBr

Article Abstract:

The stability of HBr against hydrogen elimination has been analyzed with subsequent solid-state reaction of Br2 formation in a sample with hydrogen deficiencies. The simulations suggest that the undercoordinated Br atoms in H-deficient HBr are not reactive under high pressure because of delocalization of the holes doped by H vacancies and the high diffusivity of H atoms.

Hydrogen bonding

---

An initio study of dehydroxylation-carbonation reaction on brucite surface

Article Abstract:

The sequence of events that leads to the formation of a magnesite layer, via the dehydroxylation-carbonation of brucite crystals and consequent adsorption and diffusion of carbon complexes are explained. The metadynamics methodology is employed to characterize the complex reaction pathways and depicting the related free energy surface.

Magnesium Compounds, Analysis, Carbon

Similar abstracts:

• Abstracts: Interpretation of the time constants measured by kinetic techniques in nanostructed semiconductor electrodes and dye-sensitized solar cells
• Abstracts: Temperature dependence of nuclear magnetic resonance chemical shifts of 129Xe in the alpha-cages of NaY zeolite
• Abstracts: Quantification of local environments by high-resolution (super 11)B, (super 23)Na, and (super 27)Al solid-state NMR
• Abstracts: Structures and stabilities of CaO and MgO clusters and cluster ions: an alternative interpretation of the experimental mass spectra
• Abstracts: Infrared and (super 23)Na double rotation nuclear magnetic resonance studies for intrazeolite anchoring of rhodium carbonyl clusters

This website is not affiliated with document authors or copyright owners. This page is provided for informational purposes only. Unintentional errors are possible.