t-butyl nitrite (TBN) and t-butyl alcohol (TBA) reactions on clean and O-covered Rh
Article Abstract:
The reactions of t-butyl nitrite (TBN) and t-butyl alcohol (TBA) on clean and O-covered Rh foils are investigated with the help of time-of-flight mass spectrometry temperature-programmed desorption and Auger electron spectroscopy. The t-butoxy decomposes to acetone and butene through a transiet form of the oxtametallacycle involved in TBN.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
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Size dependent reaction kinetics on supported model catalysts: a molecular beam/IRAS study of the CO oxidation on alumina-supported Pd particles
Article Abstract:
Molecular beam techniques are used in combination with IR reflection absorption spectroscopy to study the CO oxidation kinetics on oxide-supported model catalysts. In this study, size 100 Pd particles are compared with size 2700 Pd particles.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
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Two-dimensional effects on the in situ infrared spectra of CO absorbed at palladium covered Pt(111) electrode surfaces
Article Abstract:
An analysis is made of the in situ infrared spectra obtained for CO saturated palladium layers deposited on platinum. This is done by the correlation of the C-O bond with cyclic voltammogram.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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