Transient 2H-phospholes as powerful synthetic intermediates in organophosphorus chemistry
Article Abstract:
Cyclopentadienes, 2H-phospholes can act both as dienes and dienophiles. 2H-phospholes can readily deprotonated to give highly aromatic anions and can readily react with transition metal derivatives to give n5-complexes representing a diagonal phosphorus-carbon analogy.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
User Contributions:
Comment about this article or add new information about this topic:
Asymmetric hydrogenation of heteroaromatic compounds
Article Abstract:
Asymmetric hydrogenation of heteroaromatic compounds developed as a new route to saturated or partially saturated chiral heterocyclic compounds. Advances in these new compounds are presented.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2007
User Contributions:
Comment about this article or add new information about this topic:
Developing chiral ligands for asymmetric hydrogenation
Article Abstract:
The development of ligand for asymmetric hydrogenation is discussed. The development of three classes of ligands is presented and many pharmaceutically valuable chiral products are prepared.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2007
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Phosphoryl transfer enzymes and hypervalent phosphorus chemist. New features in pentacoordinate phosphorus chemistry
- Abstracts: Harris County moves forward on project Brays. Software will help determine appropriate storm-water practice. Voinovich and Carper underscore importance of proposed infrastructure commission
- Abstracts: Advanced composite panels for seismic and vibration mitigation of existing structures. Relaxation of proton conductivity and stress in proton exchange membranes under strain
- Abstracts: Ionic liquids in electrochemical devices and processes: managing interfacial electrochemistry. Structure and solvation in ionic liquids
- Abstracts: Intermolecular dynamics, interactions, and solvation in ionic liquids