Alfred Werner revisited: The coordination chemistry of anions
Article Abstract:
A series of macrocyclic receptors are designed to probe the influence of four factors, hydrogen bonding, charge, dimensionality, and topology, on anion binding. Results indicate a number of corollaries with transition-metal coordination chemistry in terms of binding concepts and geometries for anion complexes.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2005
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Organocatalytic asymmetric epoxidation of olefins by chiral ketones
Article Abstract:
Chiral ketones are shown to be effective organocatalysts for asymmetric epoxidation of olefins with broad substrate scope. The stereochemical outcome of the reaction can be rationalized by a spiro transition state model.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
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