A simple model for the diffuse double layer based on a generalized mean spherical approximation
Article Abstract:
A semiempirical method of including the effects of ionic size in a simple analytical model of the diffuse double layer is described. On the basis of guidance in the hypernetted-chain approximation, the ion-wall correlation functions are modified from their Gouy-Chapman approximations by addition of two new parameters, one is a constant relating to the osmotic pressure, and the other is related to the effect that ion size has on the thickness of the ionic atmosphere in the electrolyte system.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
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Description of vapor-liquid equilibria for CO2 in electrolyte solutions using the mean spherical approximation
Article Abstract:
The mean spherical approximation is used to describe the vapor pressure over aqueous solutions containing an electrolyte and carbon dioxide. It could be shown that vapor phase is composed in each case of more than 98 percent of carbon dioxide.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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Electron transfer kinetics of tris(1,10-phenanthroline)ruthenium(II) electrooxidation in aprotic solvents
Article Abstract:
Research is presented describing the study of tris(1,10-phenanthroline) ruthenium(II) for kinetic electron transfer.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
User Contributions:
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