Adsorption of proteins at the liquid/air interface
Article Abstract:
Protein adsorption layers at liquid/fluid interfaces were described using thermodynamic equations derived as a generalization of a novel theory which takes into account the nonideality of enthalpy and entropy of mixing. The effect of the electric charge of the protein molecules on surface pressure was also considered in the proposed theory. Results showed that the derived isotherm is highly consistent with experimental data. The values of the isotherm parameters surface area per molecule, adsorption layer thickness and electric charge of the HSA molecule are approximate to values obtained by other methods in literature.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1998
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Surface pressure isotherm for the fluid state of langmuir monolayers
Article Abstract:
The equation of state for the monolayer comprised of the molecules of different sizes is modified to describe the fluid state of the molecules monolayer. The values of molecular areas of amphiphilic molecules estimated from the fitting of experimental data to the proposed equation are found to be quiet similar to those measured in independent grazing incidence X-ray diffraction experiments.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Influence of the two-dimensional compressibility on the surface pressure isotherm and dilational elasticity of dodecyldimethylphosphine oxide
Article Abstract:
A model for the surface pressure isotherm and high frequency limit of dilational elasticity of a surfactant adsorption layers is proposed which assumes a two-dimensional compressibility of adsorbed molecules. It is observed that while this compressibility of absorbed molecules has no significant effect on the isotherm, the elasticity is enormously affected.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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- Abstracts: Hydrogen bond lifetime dynamics at the interface of a surfactant monolayer. Study of the surface thermal coefficient, bTP: evidence of phase transition at low surfactant concentrations. Example of solutions of Triton X100 in water and in water-ethylammonium nitrate media
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