Dielectric relaxation in aqueous solutions of hydrazine and hydrogen peroxide: Water structure implications
Article Abstract:
The dielectric relaxation studies of aqueous solutions of two water-like molecules, hydrazine and hydrogen peroxide, in the neighborhood of their glass transition temperatures, T(sub g), is reported. Their relaxations near T(sub g) are more nearly exponential than in most other cases, and they show essentially no secondary relaxations.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Computational study of tin-catalyzed Baeyer-Villiger reaction pathways using hydrogen peroxide as oxidant
Article Abstract:
The Baeyer-Villiger oxidation is a prominent reaction in synthetic organic chemistry due to its versatility and highly predictable regioselectivity and stereoselectivity. Several possible reaction mechanisms for tin-catalyzed Baeyer-Villiger oxidation of acetone with hydrogen peroxide are studied.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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