Dissociation of cyanogen azide: an alternative route to synthesis of carbon nitride
Article Abstract:
A study was conducted to prepare solid films on different substrates in a flow-tube reactor by upstream mixing of cyanogen azide, cyanogen or cyanogen halides supporting active nitrogen from an electrical discharge. The mixtures in helium diluent gas were determined in a stainless steel cylinder. Experimental results indicated that differences in spin symmetry or internal energy support a critical role in film growth.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1998
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Adsorption and decomposition pathways of cyanogen halides on Si(100)-(2x1)
Article Abstract:
The adsorption and surface reactions of ICN, BrCN, and CICN on the Si(100)-(2x1) surface are investigated using ab initio quantum calculations on single- and triple-dimer clusters. These cyanogen halides can physisorb into an end-on molecular species that is bound through the N to the Si cluster via dative bond.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Adsorption chemistry of cyanogen bromine and cyanogen chlorine on silicon(100)
Article Abstract:
The adsorption and decomposition of cyanogens halides, XCN (X = Br, Cl), on Si(100) is investigated utilizing X-ray photoelectron spectroscopy (XPS) and ultraviolet photoelectron spectroscopy (UPS). For submonolayer exposures, XPS indicates that the CN triple bond remains intact upon adsorption at 100k.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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