Functionalization of zeolite ZSM-5 by hydrosilylation and acetone coupling: Synthesis, MAS NMR, and theory
Article Abstract:
A two-step postsynthetic functionalization reaction of zeolite HZSM-5 that proceeds with high selectivity at room temperature is reported. The theoretical modeling using density functional theory and cluster models of the zeolite acid site has shown that both steps are exothermic and has provided theoretical chemical shift values in agreement with the experiment.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Zeolites, Usage, Spectra, Density functionals, Density functional theory
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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A novel luminescent functionalized siloxane polymer
Article Abstract:
Siloxy-conjugated hexatriene was formed as a result of acetone and tetrachlorosilane reaction. DAA, MEO and phorene get formed in different stages of the reaction.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Science & research, Cyclic crudes and intermediates, Cyclic Crude and Intermediate Manufacturing, Chlorobenzenes, Research, Electric properties, Chlorobenzene, Silicon polymers
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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Subjects list: Chemical properties, Acetone
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