Harnessing ICl reduction processes for synthesis of different BEDT-TTF-based molecular conductors

Article Abstract:

The ICl reduction process, used to form I(sub 3)(super -), I(sub 2)Cl(super -), and ICl(sub 2)(super -) anions and prepare different molecular conductors based on trihalide anions and bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) is described. It is seen that molecular conductors reveal semiconducting and metallic transport properties and that in the reaction media with polarity less than 18.4 D only the I(sub 3)(super -) anion is incorporated in the BEDT-TTF-based molecular crystals.

Cyclic Crude and Intermediate Manufacturing, Ethylene, Iodine & Compounds, Chlorides, Dichloropropane, Iodine compounds

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Sum frequency generation microscopy of microcontact-printed mixed self-assembled monolayers

Article Abstract:

The sum frequency generation imaging microscopy (SFGIM) is used to image the chemically distinct regions of a microcontact-printed monolayer surface. The SFGIM technique is able to obtain a vibrational spectrum at each point on the surface and demonstrate that the stamped area has a significant mixing with the molecules deposited from the backfilling solution.

Methods, Design and construction, Monomolecular films, Microscope and microscopy, Microscopy, Phenyl compounds

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New optical absorption band resulting from the organization of self-assembled monolayers of organic thiols on gold

Article Abstract:

Empirical evidence supporting the existence of a new optical absorption band observed when monolayers of alkylthiol are self-assembled on gold substrate is presented. The intensity of the new band has correlated well with the density of molecules and the quality of the organization of the monolayer.

Analysis, Optical properties, Reflectance spectroscopy

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