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Conformational equilibrium of Bis(trifluoromethanesulfonyl) imide anion of a room-temperature ionic liquid: Raman spectroscopic study and DFT calculations

Article Abstract:

The structure of bis(trifluoromethanesulfonyl) imide(TFSI(super minus)) in the liquid state was studied by means of Raman spectroscopy and DFL Calculations. The results concluded that a conformational equilibrium was established between the C(sub 1) and C(sub 2) conformers of TFSI(super minus) in the liquid EMI(super plus)TFSI(super -) and the C2 conformer is more favorable than the C1 one.

Author: Takamuku, Toshiyuki, Fujii, Kenta, Fujimori, Takao, Kanzaki, Ryo, Umebayashi, Yasuhiro, Ishiguro, Shin-ichi
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Sulfur Compounds, Usage, Methane, Density functionals, Density functional theory, Fluorine compounds, Chemical properties, Sulphur compounds

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Raman spectroscopic investigations of pressure-induced phase transitions in n-hexane

Article Abstract:

The Raman spectroscopic studies of linear chain n-hexane at 16 GPa which shows all-trans configuration at high-pressure phase is reported. The high-pressure phase is an orientationally disordered phase due to random freezing of the methane end group.

Author: Kavitha, G., Narayana, Chandrabhas
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
Industrial Organic Chemicals, Cyclic Crude and Intermediate Manufacturing, Hexane, Analysis, Electric properties, Spectra, Structure, Rayleigh scattering

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Subjects list: Raman spectroscopy
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