Transport properties of solid polymer electrolytes prepared from oligomeric fluorosulfonimide lithium salts dissolved in high molecular weight poly(ethylene oxide)
Article Abstract:
A series of solid polymer electrolytes is prepared from novel oligomeric fluorosulfonimide lithium salts based on the bis[(trifluoromethyl)sulfonyl]imide (TFSI) anion motif using high molecular weight poly-(ethylene oxide) (PEO) as the polymer host. The findings suggest an increased involvement of host plasticization by the larger anions and possibly also of differing degrees of ion pairing for the different chain length salts.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Laser-induced photovoltage transient studies on nanoporous TiO2 electrodes
Article Abstract:
The electron transport in electrolyte filled nanoporous TiO2 and the influence of circuit condition on the electron transport, by means of photovoltage transient are discussed. Photovoltage transients are measured with electrodes having various thicknesses, showing that the transit time was nearly proportional to the square of the electrode thickness.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Effects of lithium ion density on electron transport in nanoporous TiO2 electrodes
Article Abstract:
The transport of photogenerated electrons in nanoporous TiO2 electrodes is examined in a lithium perchlorate electrolyte solution by laser-induced photocurrent transient measurements. The diffusion coefficients of the photoelectrons are found to depend on the lithium ion concentration in the solution.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
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