Arsenate and chromate retention mechanisms on goethite. 1. Surface structure
Article Abstract:
A study aimed at determining the stability and oxyanion sorption mechanisms of arsenic and chromium is presented. Chromate and arsenate are present in the environment in high levels and prove to be very harmful to living organisms. It is deemed important to identify the reactions that will remove these contaminants from the aqueous phase, thereby limiting their mobility and bioavailability. The study utilized extended X-ray absorption fine structure (EXAFS) spectroscopy to deduce the local coordination environment of the two contaminants on the mineral goethite (alpha-FeOOH).
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1997
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Investigation of Ni sorption on pyrophyllite: an XAFS study
Article Abstract:
The local atomic structure of Ni(II) sorbed into pyrophyllite was studied using X-ray absorption fine structure spectroscopy. It was shown that the first coordination shell featured six O atoms at 2.02-2.04 anstrom. The second shell consisted of a single Ni-Al/Si distance. The number of Ni second-neighbor atoms between 2.99-3.00 angstrom increased along with Ni surface loading on pyrophyllite.
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1996
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The nature of Zn precipitates formed in the presence of pyrophyllite
Article Abstract:
Researchers from the University of Delaware studied the partitioning of zinc to pyrophyllite as a function of surface loading using x-ray absorption fine structure spectroscopy. Reaction products reveal the formation of a Zn-Al layered hydroxide surface precipitate.
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 2000
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