Modeling electrochemical deposition inside nanotubes to obtain metal-semiconductor multiscale nanocables or conical nanopores
Article Abstract:
A new physical model for the nanocable synthesis is proposed and the effects of the deposited species concentration, potential-dependent reaction rate, and nanopore dimensions on the electrochemical deposition is studied. The problem involves both the axial diffusion through the nanopore and radial transport to the nanopore surface, with a surface reaction rate that depends on the axial position and the time.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
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Effect of protein adsorption and ionic strength on the equilibrium partition coefficient of ionization macromolecules in charged nanopores
Article Abstract:
A calculation is done of the equilibrium partition coefficient of a spherical protein molecule in a nanopore consisting of ionizable carboxylic acid groups as a function of ionic strength pH, charge and size of the protein and the pore wall. The objective of the calculation is to understand the strong increase in flux around the isoelectric point of the protein molecule at 10mM ionic strength.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Transient behavior of the hydrophobic surface/water interface: from nanobubbles to organic layer
Article Abstract:
The formation and characterization of water-depleted layer at a hydrophobic surface/water interface is reported. The evolution from nanobubbles to an organic layer is influenced by the surface energy of the liquid media.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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