Equation of state for the phase coexistence region of insoluble monolayers under consideration of the entropy nonideality
Article Abstract:
The generalization of the equation of state for the monolayer with a fluid/condensed phase transition derived in the framework of a quasichemical approach is reported. The calculated results from equations provide insight into entropy nonideality of mixing of the monomers and clusters of amphiphilic molecules.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2008
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Dynamics and equilibrium of the penetration of soluble cetyltrimethylammonium bromide into Langmuir monolayer of arachidic acid under different pH conditions
Article Abstract:
Experimental studies of the dynamics and equilibrium of the penetration of the soluble cationic surfactant cetyltrimethylammonium bromide (CTAB) into arachidic acid monolayers are reported. A new theoretical model is proposed involving the enthalpic nonideality of the mixed monolayer.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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