Transport coefficients, Raman Spectroscopy, and computer simulation of lithium salt solution in an ionic liquid
Article Abstract:
Thermal properties, ionic conductivity and self-diffusion coefficients of lithium [Li] salt solutions in a room-temperature ionic liquid (RTIL), bis(trifluoromethanesulfonyl)imide anion [BMMI][TFSI] are determined. The studies indicate the formation of aggregates in which the Li ion coordination with oxygen atom of TFSI anions changes with the Li ion concentration, resulting in a change in the RTIL structure and a reduction of the diffusion coefficient for all the species.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2008
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Lithium intercalation for phenyl-capped aniline dimmers: A study by photoelectron spectroscopy and quantum chemical calculations
Article Abstract:
Structural and electronic properties of pristine and lithium-intercalated, phenyl-capped aniline dimmers as a model for the lithium-polyaniline system were studied by photoelectron spectroscopy and quantum chemical calculations. It was found that the electronic structure of reduced and oxidized forms of oligoanilines is only weakly affected by isomerism.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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