Asymmetric photoreactions within zeolites: role of confinement and Alkali Metal Ions
Article Abstract:
Four strategies for asymmetric induction in organic photochemistry that derive their success from the use of a confined reaction cavity is explored. Examination of the zeolite interior suggests that the most likely factor responsible for the change in diastereomeric excess(de) or enantiomeric excess(ee) is the difference in conformational preference for the reactant molecules.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2003
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Asymmetric synthesis and organometallic chemistry of functionalized phosphines containing stereogenic phosphorus centers
Article Abstract:
The overview of the work in the area of transforming P-stereogenic mono- and diphosphine ligands is given. The details concerning the series of organometallic reagents are discussed.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
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Analogies between Boron and Carbon
Article Abstract:
Even though carbon and boron are neighbors in the periodic table they differ quite a lot. Many similarities between the two that were not noticed earlier are presented.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2003
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