Exploiting the synergy between coordination chemistry and molecular imprinting in the quest for new catalysts
Article Abstract:
The synthesis of transition metal active sites by the molecular imprinting of polymerizable metal complexes into highly crosslinked organic polymers is described. The important goal of designer catalysts is to achieve reaction selectivites and reactivities not obtainable with traditional homo- or heterogeneous catalysts.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
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Do new century catalysts unracel the mechanism of stereocontrol of old Ziegler-Natta Catalysts?
Article Abstract:
The models developed to explain the origin of stereoselectivity for the well-defined new octahedral systems is compared. The models developed years ago is revisited to explain the experimental iso- and syndiospecificity to the traditional Ziegler-Natta catalysts.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
User Contributions:
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