Rate of interfacial electron transfer through the 1,2,3-triazole linkage

Article Abstract:

The electron-transfer rates for a number of assemblies of azide-terminated thiol monolayers coupled to different redox species to form the 1,2,3-triazole linkage are reported. The ability to vary the rate of electron transfer to many different redox species over many orders of magnitude by using modular coupling chemistry has provided a convenient way to study and control the delivery of electrons to multielectron redox catalysts and similar interfacial systems that require controlled delivery of electrons.

United States, All Other Basic Organic Chemical Manufacturing, Industrial Organic Chemicals, Mercaptans, Monomolecular films, Thiols, Chemical properties, Atomic properties

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Charge reduction in electrosprays: Slender nanojets as intermediates

Article Abstract:

Molecular dynamics simulations were used to study charge reduction in electrosprayed liquids through the formation of slender nanojet intermediates. Depending on the overall charge, simulations showed three basic scenarios for nanojet evolution.

Molecular dynamics

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